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Updated: Jul 9, 2026

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
A helix-turn-helix supersecondary structure based on oligo(phenanthroline dicarboxamide)s
Hai-Yu Hu1, Jun-Feng Xiang, Yong Yang
1Beijing National Laboratory for Molecular Sciences, Center for Chemical Biology, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China.
Abstract:
An artificial helix-turn-helix (HTH) supersecondary structure based on the oligo(phenanthroline dicarboxamide)s, in which the 2,2'-dimethoxy-1,1'-binaphthyl-6,6'-diamine subunit was utilized as the turn to impart a bias in the twist sense of the supersecondary structure, was reported. The HTH structure has been demonstrated by UV/vis, NMR, CD spectra, and X-ray crystal analysis.
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