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Molecular transformations of unsaturated thiacrown ethers

Takahiro Tsuchiya1, Yosuke Okada, Toshio Shimizu

  • 1Department of Chemistry, Graduate School of Sciences and Engineering, Tokyo Metropolitan University, Minami-ohsawa, Hachioji, Tokyo 192-0397, Japan.

The Journal of Organic Chemistry
|December 12, 2007
PubMed
Summary

Unsaturated thiacrown ethers were oxidized to sulfoxides using m-CPBA or t-BuOCl. Further reactions yielded cis-trans isomers or acetals, showcasing diverse chemical transformations of these cyclic thioethers.

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