Hydrothermal in situ synthesis and characterization of Cu(II) complexes
Danfeng Weng1, Weihua Mu, Xiangjun Zheng
1Department of Chemistry, Beijing Normal University, Beijing, 100875 P. R. China.
Abstract:
The hydrothermal in situ Cu(II)/2,3-pyrazine dicarboxylic acid reactions at 100 and 140 degrees C result in Cu(II) 3-hydroxy-2-pyrazinecarboxylate and oxalate complexes, respectively. This is the first example of a combination of experimental and theoretical study on in situ metal/ligand reactions under hydro- and solvothermal conditions.
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