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Measuring the work function of carbon nanotubes with thermionic method.

Peng Liu1, Qin Sun, Feng Zhu

  • 1Department of Physics and Tsinghua-Foxconn Nanotechnology Research Center, Tsinghua University, Beijing 100084, China. Liup01@mails.thu.edu.cn

Nano Letters
|January 30, 2008
PubMed
Summary
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The work function of carbon nanotubes (CNTs) is consistent across sidewalls regardless of diameter or wall number. However, CNT tips exhibit a lower work function than sidewalls, indicating non-uniform work function distribution.

Area of Science:

  • Materials Science
  • Nanotechnology
  • Surface Science

Background:

  • The work function of carbon nanotubes (CNTs) is a critical property influencing their electronic behavior.
  • Previous studies suggested potential dependencies of CNT work function on diameter and wall structure, as well as variations between tips and sidewalls.

Purpose of the Study:

  • To experimentally measure and compare the work function of single-walled, double-walled, and multiwalled carbon nanotubes.
  • To investigate the influence of CNT diameter and wall number on work function.
  • To determine if CNT tips have a different work function compared to their sidewalls.

Main Methods:

  • Thermionic emission measurements were conducted on bundles of single-walled, double-walled, and multiwalled carbon nanotubes.

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  • The measurements focused on the middle sections of the CNT bundles to analyze sidewall properties.
  • Comparative analysis was performed on bundles with and without exposed tips in the measurement area.
  • Main Results:

    • The sidewall work function for all investigated CNT types (single-walled, double-walled, multiwalled) was found to be consistently around 4.7-4.9 eV.
    • No significant influence of CNT diameter or the number of walls on the sidewall work function was observed.
    • Bundles with exposed tips in the middle exhibited a lower measured work function compared to those without tips, indicating a smaller work function for tips.

    Conclusions:

    • The work function of carbon nanotube sidewalls is largely independent of diameter and wall number.
    • Carbon nanotube tips possess a lower work function than their sidewalls.
    • The presence of tips leads to a non-uniform work function distribution along the carbon nanotube bundle, affecting thermionic emission characteristics.