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Colloidal precipitates01:09

Colloidal precipitates

The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
Colloids03:22

Colloids

Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
The Colloidal State01:29

The Colloidal State

The formation of a colloidal system is exemplified by an aqueous solution containing Cl− ions is introduced to another containing Ag+ ions, resulting in the precipitation of solid AgCl as extremely tiny crystals. Instead of settling out as a filterable precipitate, these crystals remain suspended in the liquid, showcasing a colloidal system.A colloidal system involves colloidal particles within the approximate range of 1 to 1000 nm in at least one dimension, dispersed in a medium called the...
Cohesion01:07

Cohesion

Cohesion is the attraction between molecules of the same type, such as water molecules. Water molecules have an overall neutral charge but are polar molecule. An oxygen atom in one water molecule has a partial negative charge that can bind to a hydrogen atom with a partial positive charge in a second water molecule, forming a hydrogen bond. Each water molecule can form up to four hydrogen bonds with other water molecules. Hydrogen bonds are responsible for water's cohesive nature.
On a surface,...
Van der Waals Interactions01:24

Van der Waals Interactions

Atoms and molecules interact with each other through intermolecular forces. These electrostatic forces arise from attractive or repulsive interactions between particles with permanent, partial, or temporary charges. The intermolecular forces between neutral atoms and molecules are ion–dipole, dipole–dipole, and dispersion forces, collectively known as van der Waals forces.Polar molecules have a partial positive charge on one end and a partial negative charge on the other end of the molecule,...
Intermolecular Forces03:13

Intermolecular Forces

Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen bonds, and dispersion...

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Related Experiment Video

Updated: Jul 7, 2026

Real-Time Force Measurement Between Emulsion Droplets During Enzymatic Breakdown
04:56

Real-Time Force Measurement Between Emulsion Droplets During Enzymatic Breakdown

Published on: June 27, 2025

Decompressing emulsion droplets favors coalescence.

Nicolas Bremond1, Abdou R Thiam, Jérôme Bibette

  • 1UPMC Univ. Paris 06, ESPCI, CNRS, 10 rue Vauquelin, 75005 Paris, France. Nicolas.Bremond@espci.fr

Physical Review Letters
|February 1, 2008
PubMed
Summary

Emulsion destabilization occurs counterintuitively during droplet separation, not impact, due to nipple formation. This finding impacts understanding of droplet fusion and emulsion stability under flow conditions.

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Published on: July 3, 2018

Area of Science:

  • Fluid dynamics
  • Colloid and surface chemistry
  • Microfluidics

Background:

  • Emulsion destabilization is crucial in various industrial processes.
  • Understanding droplet coalescence under flow is essential for controlling emulsion properties.
  • Previous studies often focused on impact-induced coalescence.

Purpose of the Study:

  • To investigate the fundamental mechanisms of emulsion destabilization under flow.
  • To analyze the droplet coalescence process in a controlled microfluidic environment.
  • To identify the key factors influencing droplet fusion.

Main Methods:

  • Utilizing a microfluidic device to generate and control droplet pairs.
  • Observing droplet interactions and coalescence events using high-resolution imaging.
  • Analyzing the dynamics of droplet interfaces during separation and impact phases.

Main Results:

  • Demonstrated that droplet coalescence occurs during the separation phase, not impact.
  • Identified the formation of facing nipples that accelerate interface connection and fusion.
  • Showed that surfactant-stabilized emulsions can be destabilized by forced separation.
  • Observed a cascade of coalescence events driven by surface tension in compact droplet systems.

Conclusions:

  • Droplet separation, rather than impact, is the critical phase for coalescence in this microfluidic system.
  • The formation of nipples during separation is a key mechanism hastening droplet fusion.
  • Forced separation can overcome stabilizing effects of surfactants, leading to destabilization.
  • The identified fusion mechanism has implications for controlling emulsion behavior in confined systems.