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Published on: May 27, 2018
Probing the electron delocalization in liquid water and ice at attosecond time scales
D Nordlund1, H Ogasawara, H Bluhm
1Stanford Synchrotron Radiation Laboratory, P.O. Box 20450 Stanford, California 94309, USA.
Abstract:
We determine electron delocalization rates in liquid water and ice using core-hole decay spectroscopy. The hydrogen-bonded network delocalizes the electrons in less than 500 as. Broken or weak hydrogen bonds--in the liquid or at the surface of ice--provide states where the electron remains localized longer than 20 fs. These asymmetrically bonded water species provide electron traps, acting as a strong precursor channel to the hydrated electron.
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