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DNA linker-mediated crystallization of nanocolloids

Huiming Xiong1, Daniel van der Lelie, Oleg Gang

  • 1Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973, USA.

Journal of the American Chemical Society
|February 6, 2008
PubMed
Abstract

No abstract available in PubMed .

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The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...