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Published on: March 24, 2019
On the anisotropy of the magnetic properties of CsYbZnSe3
George H Chan1, Changhoon Lee, Dadi Dai
1Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, USA.
Abstract:
DC magnetic susceptibility measurements on CsYbZnSe 3 show a broad magnetic transition at approximately 10 K and pronounced differences between zero-field-cooled and field-cooled data that lead to experimental effective magnetic moments of 4.26(5) BM and 4.39(4) BM, respectively. Specific heat measurements confirm that there is neither long-range ordering nor a phase transition between 1.8 and 380 K. First-principles electronic structure calculations with and without inclusion of spin-orbit coupling effects show that the spins of CsYbZnSe 3 prefer to orient along [010] rather than along either [100] or [001] of this orthorhombic material and that the spin exchange between adjacent Yb3+ ions along [100] is substantially antiferromagnetic. The magnetic properties of CsYbZnSe 3 are best described by an Ising uniform antiferromagnetic chain model.
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