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Gravimetry: Overview

Gravimetric analysis is a quantitative method where the analyte is isolated and weighed directly or after conversion into a substance of known composition. Gravimetric analysis can be classified as precipitation, electrogravimetry, volatilization, and particulate gravimetry, based on the method used to isolate the analyte.
In precipitation gravimetry, the analyte is converted into a precipitate and weighed. For example, the silver content in a sample can be estimated by precipitating and...

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Understanding Dissolved Organic Matter Biogeochemistry Through In Situ Nutrient Manipulations in Stream Ecosystems
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Geochemical tracers to evaluate hydrogeologic controls on river salinization.

Stephanie J Moore1, R L Bassett, Beiling Liu

  • 1Daniel B. Stephens & Associates Inc., 6020 Academy NE, Ste. 100, Albuquerque, NM 87109-3315, USA. smoore@dbstephens.com

Ground Water
|February 13, 2008
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Summary

River salinization in arid regions is complex. This study found deep groundwater inflow, not just agriculture, is the main cause of increased salinity in the Lower Rio Grande.

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Area of Science:

  • Environmental Science
  • Hydrogeology
  • Geochemistry

Background:

  • River salinization is a global issue in arid/semiarid regions.
  • Historically, salinity sources include evaporation, irrigation, erosion, and groundwater inflow.

Purpose of the Study:

  • To identify and quantify anthropogenic vs. natural salinity sources in the Lower Rio Grande.
  • To investigate the dominant contributors to river salinization in the New Mexico-Texas border region.

Main Methods:

  • Utilized a conceptual model to identify water and salinity sources.
  • Designed a sampling plan to characterize identified sources.
  • Analyzed stable isotopes (B, S, O, H) and strontium isotopes, alongside basic chemical data.

Main Results:

  • Confirmed that deep groundwater inflow is the dominant source of salinity.
  • Stable isotopic ratios provided distinctive signatures for deep groundwater.
  • Evapotranspiration and agricultural processes alone cannot explain the observed salinization.

Conclusions:

  • Deep groundwater inflow is the primary driver of salinization in the Lower Rio Grande.
  • Isotopic and geochemical tracers are effective tools for identifying multiple solute sources in river systems.