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Related Concept Videos

X-ray Crystallography02:18

X-ray Crystallography

The size of the unit cell and the arrangement of atoms in a crystal may be determined from measurements of the diffraction of X-rays by the crystal, termed X-ray crystallography.
Diffraction
Diffraction is the change in the direction of travel experienced by an electromagnetic wave when it encounters a physical barrier whose dimensions are comparable to those of the wavelength of the light. X-rays are electromagnetic radiation with wavelengths about as long as the distance between neighboring...
Determination of Crystal Structures01:29

Determination of Crystal Structures

In the late 1800s, the revelation that light extended beyond visible wavelengths led to the discovery of X-rays by Wilhelm Roentgen. Recognized as high-energy electromagnetic radiation with short wavelengths, X-rays prompted exploration into their interaction with crystals. Max von Laue proposed in 1912 that the periodic arrangement of atoms, ions, or molecules in crystals would cause them to diffract X-rays, a hypothesis confirmed through experiments with copper sulfate and zinc sulfide...
IR Spectrometers01:25

IR Spectrometers

There are two main infrared (IR) spectrophotometers: dispersive IR spectrometers and Fourier transform infrared (FTIR) spectrometers. In a dispersive IR spectrometer, a beam of infrared radiation produced by a hot wire is divided into two parallel equal-intensity beams using mirrors. One beam passes through the sample, while another is a reference beam. The beams then move through the monochromator, which separates the radiations into a continuous spectrum of different frequencies. The...
IR Spectroscopy: Hooke's Law Approximation of Molecular Vibration01:16

IR Spectroscopy: Hooke's Law Approximation of Molecular Vibration

A covalently bonded heteronuclear diatomic molecule can be modeled as two vibrating masses connected by a spring. The vibrational frequency of the bond can be expressed using an equation derived from Hooke's law, which describes how the force applied to stretch or compress a spring is proportional to the displacement of the spring. In this case, the atoms behave like masses, and the bond acts like a spring.
According to Hooke's law, the vibrational frequency is directly proportional to the...
Attenuated Total Reflectance (ATR) Infrared Spectroscopy: Overview01:13

Attenuated Total Reflectance (ATR) Infrared Spectroscopy: Overview

Attenuated total reflectance (ATR) infrared spectroscopy is a powerful analytical technique used to study the composition of materials. It is widely employed in chemistry, materials science, forensic science, and other fields where sample characterization is required. ATR has several advantages over traditional transmission IR spectroscopy, including the requirement of little to no sample preparation and the ability to analyze a wide range of samples.
The ATR process begins by directing a beam...
Infrared (IR) Spectroscopy: Overview01:09

Infrared (IR) Spectroscopy: Overview

When electromagnetic radiation passes through a material, atoms or molecules transition from a lower to a higher energy state by absorbing radiation corresponding to the energy difference between the two states. The absorption of infrared (IR) radiation causes transitions between vibrational energy levels in a molecule. Therefore, IR spectroscopy is a useful analytical tool for determining the molecular structure of molecules.
Different compounds display unique properties due to their...

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Related Experiment Video

Updated: Jul 7, 2026

Hyperspectral Imaging as a Tool to Study Optical Anisotropy in Lanthanide-Based Molecular Single Crystals
07:24

Hyperspectral Imaging as a Tool to Study Optical Anisotropy in Lanthanide-Based Molecular Single Crystals

Published on: April 14, 2020

Optically anisotropic crystalline grisms for astronomical spectrographs.

N Ebizuka, M Iye, T Sasaki

    Applied Optics
    |February 13, 2008
    PubMed
    Summary

    Lithium niobate (LiNbO3) grisms offer high spectral resolution for astronomical spectrographs. Their high refractive index and transmission optics enable powerful new dispersing elements for visible to near-infrared observations.

    Area of Science:

    • Optics and Astronomical Instrumentation
    • Materials Science

    Background:

    • Traditional dispersing elements in astronomical spectrographs face limitations in achieving high spectral resolution.
    • The need for advanced optical components for visible to near-infrared spectroscopy is critical for astronomical research.

    Purpose of the Study:

    • To introduce crystalline Lithium Niobate (LiNbO3) grisms and hybrid grisms as novel dispersing elements.
    • To evaluate their potential for high spectral resolution in transmission astronomical spectrographs.
    • To describe the fundamental principles and limitations of using LiNbO3 grisms.

    Main Methods:

    • Investigated crystalline LiNbO3 grisms and hybrid grisms composed of LiNbO3 transmission gratings and ZnS prisms.
    • Analyzed the optical properties, specifically refractive indices and birefringence, of these materials.

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    Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
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    Published on: June 7, 2018

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    Last Updated: Jul 7, 2026

    Hyperspectral Imaging as a Tool to Study Optical Anisotropy in Lanthanide-Based Molecular Single Crystals
    07:24

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    Published on: June 7, 2018

  • Assessed their performance as dispersing elements in simulated spectrograph designs.
  • Main Results:

    • Demonstrated that LiNbO3 grisms possess high refractive indices suitable for high spectral resolution.
    • Showcased the potential of both crystalline and hybrid LiNbO3 grisms for visible to near-infrared astronomical spectrographs.
    • Identified inherent birefringence in LiNbO3 as a factor limiting spectral separation.

    Conclusions:

    • Crystalline and hybrid LiNbO3 grisms are powerful new dispersing elements for astronomical spectrographs.
    • Their high refractive indices facilitate high spectral resolution in transmission optics.
    • Understanding and mitigating birefringence is key to optimizing spectral separation in LiNbO3-based grisms.