An index for quantifying the aerobic reactivity of municipal solid wastes and derived waste products

The organic matter contained in municipal solid waste (MSW) and in the MSW fractions obtained by mechanical separation has strong environmental impact when the waste is used as landfill. This is partly due to the biological activity that occurs under anaerobic conditions. Negative effects on the environment include unpleasant odors, biogas, leachate and biomass self-heating. Measuring the biological reactivity of waste with the help of indicators is an important tool to prevent waste impact. The aim of this study was to develop an index capable of describing the aerobic reactivity of waste, using both biological and chemical indicators. To develop this index, 71 MSW and MSW-product samples, including biologically treated MSW and mechanically separated MSW fractions, were analyzed. Fifty of the 71 samples analyzed represented MSWs and their derived products collected from a number of Italian waste plants and sites. The remaining 21 were MSW samples collected at different times during 8 different full-scale aerobic biological processes in four treatment plants used to reduce the biological reactivity of wastes. Five of these processes used the entire (unsorted) MSW, while the remaining three used the organic fraction of the MSW obtained by mechanical pre-treatment (waste sieving). Respirometric activity (Dynamic Respiration Index, DRI) and eluates characterization (chemical oxygen demand--COD, and 5 days biological oxygen demand--BOD5) were used as indicators of waste strength, as they had previously been reported to be indirect measures of waste impact on landfill. Summarizing all studied indicators, Principal Component Analysis (PCA) was used to develop the Putrescibility Index (Ip). The results revealed Ip index of 204+/-33 (mean+/-standard deviation) and 159+/-14 for the organic fraction of MSW and MSW untreated waste respectively, and of 106+/-16 and 101+/-22 for the corresponding biologically treated waste.