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Updated: Jul 7, 2026

Printing Fabrication of Bulk Heterojunction Solar Cells and In Situ Morphology Characterization
07:32

Printing Fabrication of Bulk Heterojunction Solar Cells and In Situ Morphology Characterization

Published on: January 29, 2017

Processing additives for improved efficiency from bulk heterojunction solar cells.

Jae Kwan Lee1, Wan Li Ma, Christoph J Brabec

  • 1Center for Polymers and Organic Solids, University of California at Santa Barbara, Santa Barbara, California 93106, USA.

Journal of the American Chemical Society
|February 22, 2008
PubMed
Summary
This summary is machine-generated.

Researchers identified criteria for processing additives in bulk heterojunction (BHJ) solar cells. Using 1,8-diiodooctane, BHJ solar cell efficiency improved significantly, demonstrating effective morphology control.

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Area of Science:

  • Materials Science
  • Organic Electronics
  • Photovoltaics

Background:

  • Bulk heterojunction (BHJ) solar cells require precise morphology control for optimal performance.
  • Processing additives play a crucial role in achieving desired BHJ nanostructures.
  • Existing additives often lack the ideal properties for efficient morphology control.

Purpose of the Study:

  • To identify key criteria for effective processing additives in BHJ solar cells.
  • To investigate 1,8-di(R)octanes as novel processing additives.
  • To enhance the power conversion efficiency of BHJ solar cells through improved morphology.

Main Methods:

  • Defined two criteria for processing additives: selective fullerene solubility and higher boiling point than the host solvent.
  • Synthesized and tested various 1,8-di(R)octanes as processing additives.
  • Fabricated and characterized BHJ solar cells with and without the investigated additives.

Main Results:

  • Demonstrated that 1,8-di(R)octanes with appropriate functional groups can effectively control BHJ morphology via selective fullerene solubility.
  • Identified 1,8-diiodooctane as the most effective additive among the tested compounds.
  • Achieved a significant power conversion efficiency increase from 3.4% to 5.1% in BHJ solar cells using 1,8-diiodooctane.

Conclusions:

  • The identified criteria are effective for selecting processing additives for BHJ solar cells.
  • 1,8-diiodooctane is a promising processing additive for enhancing BHJ solar cell performance.
  • Selective fullerene solubility and high boiling point are critical for controlling BHJ morphology and improving device efficiency.