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Published on: September 6, 2019
Unusual synthesis of carbohydrate sec-sec ether-linked pseudodisaccharides
Tashfeen Akhtar1, Lars Eriksson, Ian Cumpstey
1Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, S-106 91 Stockholm, Sweden.
Abstract:
In this paper, we describe the synthesis of sec-sec ether-linked pseudodisaccharides by the coupling of various secondary carbohydrate alcohols with di-O-isopropylidene allose 3-O-triflate. Reactions proceeded with inversion of configuration to give the 3-substituted di-O-isopropylidene glucose derivatives. The crystal structure of a sec-sec ether-linked pseudodisaccharide is reported.
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