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Updated: Jul 7, 2026

Measurement and Analysis of Atomic Hydrogen and Diatomic Molecular AlO, C2, CN, and TiO Spectra Following Laser-induced Optical Breakdown
Published on: February 14, 2014
Radiative, collisional, and predissociative effects in CH laser-induced-fluorescence flame thermometry
1Molecular Physics Laboratory, SRI International, Menlo Park, California 94025, USA. luque@mplvax.sri.com
Abstract:
Laser-induced fluorescence of the CH radical is used to determine the flame-front temperature of an 8-Torr premixed CH(4)/O(2) flame. The A (2)D-X (2)Delta (0, 0) and B (2)Sigma- - X (2)II (0, 0) bands give values of 1960 +/- 60 and 1920 +/- 70 K, respectively. This is an improvement over a previous study that found discrepancies up to 20% between these bands. New rotational-level-dependent transition probabilities are the main reason for this improvement. The weaker off-diagonal bands A-X (0, 1) and B-X (0, 1) yield temperatures of 1930 +/- 90 and 1830 +/- 100 K, respectively. The influence of rotational transfer on the predissociated levels that have N' > in B (2)Sigma-, v'= 0 was investigated with fluorescence scans and a statistical power-gap law model of the relaxation; deviations up to 8% in temperature can occur because of this process.
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