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![The Synthesis of [Sn10(Si(SiMe3)3)4]2- Using a Metastable Sn(I) Halide Solution Synthesized via a Co-condensation Technique](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F54498.jpg&w=3840&q=50)
The Synthesis of [Sn10(Si(SiMe3)3)4]2- Using a Metastable Sn(I) Halide Solution Synthesized via a Co-condensation Technique
Published on: November 28, 2016
Synthesis, spectral characterization and bio-analysis of some organotin(IV) complexes
Wajid Rehman1, Musa Kaleem Baloch, Amin Badshah
1Department of Chemistry, Hazara University, Mansehra, Pakistan. sono_waj@yahoo.com
Abstract:
Five novel organotin(IV) derivatives have been synthesized by refluxing trimethyl, triethyl, tributyl, and triphenyl and tribenzyltin chloride with Schiff base derived from salicylaldehyde and adenine. These compounds were characterized by spectroscopic (IR, (1)H, (13)C, (119)Sn-NMR, (119m)Sn Mössbauer) techniques and elemental analysis. Based on these results, trigonal bipyramidal geometry is suggested. The synthesized compounds were also treated with various microorganisms and found to be active.
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