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Design, synthesis and antiproliferative properties of oligomers with chromophore units linked by amide backbones

Josep Farrera-Sinfreu1, Anna Aviñó, Isabel Navarro

  • 1Combinatorial Chemistry Unit, Barcelona Scientific Park (PCB), Josep Samitier 1-5, E-08028 Barcelona, Spain.

Bioorganic & Medicinal Chemistry Letters
|March 7, 2008
PubMed

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The reaction of weakly electrophilic aryldiazonium (also called arenediazonium) salts with highly activated aromatic compounds leads to the formation of products with an —N=N— link, called an azo linkage. This reaction, presented in Figure 1, is known as diazo coupling and occurs without the loss of the nitrogen atoms of the aryldiazonium salt. Highly activated aromatic compounds such as phenols or arylamines favor the diazo coupling reaction. The coupling generally occurs at the para position.