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Quasi-seeded growth of ligand-tailored PbSe nanocrystals through cation-exchange-mediated nucleation

Maksym V Kovalenko1, Dmitri V Talapin, Maria Antonietta Loi

  • 1Institute of Semiconductor and Solid State Physics, University of Linz, Altenbergerstrasse 69, 4040 Linz, Austria. maksym.kovalenko@jku.at

Angewandte Chemie (International Ed. in English)
|March 14, 2008
PubMed
Abstract

No abstract available in PubMed .

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The cationic polymerization mechanism consists of three steps: initiation, propagation, and termination. In the initiation step of the polymerization process, the π bond of a monomer gets protonated by the Lewis acid catalyst, which is formed from boron trifluoride and water. The protonation of the π bond generates a carbocation stabilized by the electron‐donating group. In the propagation step, the π bond of the second monomer acts as a nucleophile and attacks the generated carbocation,...

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