Related Experiment Video
Updated: Jul 6, 2026

07:44
Resonance Raman Spectroscopy of Extreme Nanowires and Other 1D Systems
Published on: April 28, 2016
Electron-pair resonance in the coulomb blockade
Eran Sela1, H-S Sim, Yuval Oreg
1Department of Condensed Matter Physics, Weizmann Institute of Science, Rehovot, 76100, Israel.
Physical Review Letters
|March 21, 2008
Summary
We investigated electron pair transfer and Coulomb repulsion effects on cotunneling currents. This reveals new ionization resonance peaks and structures in Coulomb blockade diamonds.
Area of Science:
- Condensed Matter Physics
- Quantum Transport
Background:
- Cotunneling current describes electron transport through localized states.
- Coulomb repulsion significantly impacts electron behavior in quantum systems.
Purpose of the Study:
- To investigate many-body corrections to cotunneling current.
- To analyze the impact of Coulomb repulsion on electron pair transfer.
Main Methods:
- Theoretical study of cotunneling current at large bias voltages.
- Analysis of the third derivative of current with respect to voltage.
Main Results:
- Identified ionization resonance peaks due to electron pair transfer.
- Located these peaks at eV=+/-2epsilon(d)/3.
- Predicted new structures within Coulomb blockade diamonds.
Conclusions:
- Many-body effects, specifically Coulomb repulsion, introduce observable features in cotunneling.
- These findings enhance the understanding of electron transport in localized states.
Related Concept Videos
Double Resonance Techniques: Overview
Double resonance techniques in Nuclear Magnetic Resonance (NMR) spectroscopy involve the simultaneous application of two different frequencies or radiofrequency pulses to manipulate and observe two distinct nuclear spins. One important application of double resonance is spin decoupling, which selectively suppresses coupling with one type of nucleus while observing the NMR signal from another nucleus, simplifying the spectrum and enhancing resolution.
Spin decoupling is usually achieved by...
Spin decoupling is usually achieved by...
¹H NMR: Long-Range Coupling
The coupling interactions of nuclei across four or more bonds are usually weak, with J values less than 1 Hz. While these are usually not observed in spectra, the presence of multiple bonds along the coupling pathway can result in observable long-range coupling.
In alkenes, spin information is communicated via σ–π overlap, as seen in allylic (four-bond) and homoallylic (five-bond) couplings. These coupling interactions are stronger when the σ bond is parallel to the alkene π orbitals.
In alkenes, spin information is communicated via σ–π overlap, as seen in allylic (four-bond) and homoallylic (five-bond) couplings. These coupling interactions are stronger when the σ bond is parallel to the alkene π orbitals.
Resonance and Hybrid Structures
According to the theory of resonance, if two or more Lewis structures with the same arrangement of atoms can be written for a molecule, ion, or radical, the actual distribution of electrons is an average of that shown by the various Lewis structures.
Resonance Structures and Resonance Hybrids
The Lewis structure of a nitrite anion (NO2−) may actually be drawn in two different ways, distinguished by the locations of the N–O and N=O bonds.
Resonance Structures and Resonance Hybrids
The Lewis structure of a nitrite anion (NO2−) may actually be drawn in two different ways, distinguished by the locations of the N–O and N=O bonds.
Resonance
The Lewis structure of a nitrite anion (NO2−) may actually be drawn in two different ways, distinguished by the locations of the N-O and N=O bonds.
Coulomb's Law
Experiments with electric charges have shown that if two objects each have an electric charge, they exert an electric force on each other. The magnitude of the force is linearly proportional to the net charge on each object and inversely proportional to the square of the distance between them. The direction of the force vector is along the imaginary line joining the two objects and is dictated by the signs of the charges involved.
Newton's third law applies to the Coulomb force — the force on...
Newton's third law applies to the Coulomb force — the force on...
Electron Paramagnetic Resonance (EPR) Spectroscopy: Organic Radicals
Ideally, an unpaired electron shows a single peak in the EPR spectrum due to the transition between the two spin energy states. However, coupling interactions can occur between the spins of the unpaired electron and any neighboring spin-active nuclei. This hyperfine coupling results in hyperfine splitting, where the EPR signal is split into multiplets. The signals split into 2nI + 1 peaks, where n is the number of equivalent nuclei and I is the nuclear spin. These splitting patterns provide...

