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Related Experiment Videos

Quantum-sized gold clusters as efficient two-photon absorbers.

Guda Ramakrishna1, Oleg Varnavski, Junhyung Kim

  • 1Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, USA.

Journal of the American Chemical Society
|March 25, 2008
PubMed
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Gold nanoclusters exhibit strong two-photon absorption, with record cross-sections for quantum-sized clusters. These properties make them ideal for advanced applications like two-photon imaging and optical power limiting.

Area of Science:

  • Nanotechnology
  • Materials Science
  • Quantum Chemistry

Background:

  • Gold clusters exhibit unique optical properties.
  • Two-photon absorption (TPA) is crucial for advanced optical applications.

Purpose of the Study:

  • Investigate the two-photon absorption properties of gold clusters.
  • Determine TPA cross-sections for various gold cluster sizes.
  • Explore potential applications of these clusters.

Main Methods:

  • Two-photon excited fluorescence spectroscopy.
  • Time-resolved fluorescence upconversion measurements.
  • Systematic variation of gold cluster size (Au25 to Au2406).

Main Results:

  • Au25 clusters show a TPA cross-section of 2700 GM at 1290 nm.

Related Experiment Videos

  • Visible fluorescence, two-photon allowed, observed in small gold clusters.
  • Record high TPA cross-sections measured for quantum-sized gold clusters.
  • Conclusions:

    • Gold nanoclusters possess significant two-photon absorption capabilities.
    • Quantum-sized gold clusters are promising for two-photon imaging.
    • Potential applications include optical power limiting and lithography.