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Flame Experiments at the Advanced Light Source: New Insights into Soot Formation Processes
Published on: May 26, 2014
Ultraviolet-visible bulk optical properties of randomly distributed soot
J B Renard1, E Hadamcik, C Brogniez
1Laboratoire de Physique et Chimie de l'Environnement, 3A Avenue de la Recherche Scientifique, F-45071 Orleans Cedex 2, France.
Abstract:
The presence of soot in the lower stratosphere was recently established by in situ measurements. To isolate their contribution to optical measurements from that of background aerosol, the soot's bulk optical properties must be determined. Laboratory measurements of extinction and polarization of randomly distributed soot were conducted. For all soot, measurements show a slight reddening extinction between 400 and 700 nm and exhibit a maximum of 100% polarization at a scattering angle of 75 +/- 5 degrees. Such results cannot be reproduced by use of Mie theory assumptions. The different optical properties of soot and background stratospheric aerosol could allow isolation of soot in future analyses of stratospheric measurements.
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