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Novel biologically potent diorganosilicon(IV) complexes of indole-2,3-dione derivatives

R V Singh1, Pooja Nagpal

  • 1Department of Chemistry, University of Rajasthan, Jaipur 302 004, India. kudiwal@datainfosys.net

Bioinorganic Chemistry and Applications
|March 28, 2008
PubMed

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The reaction of weakly electrophilic aryldiazonium (also called arenediazonium) salts with highly activated aromatic compounds leads to the formation of products with an —N=N— link, called an azo linkage. This reaction, presented in Figure 1, is known as diazo coupling and occurs without the loss of the nitrogen atoms of the aryldiazonium salt. Highly activated aromatic compounds such as phenols or arylamines favor the diazo coupling reaction. The coupling generally occurs at the para position.
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Isomerism in Complexes
Isomers are different chemical species that have the same chemical formula. Structural isomerism of coordination compounds can be divided into two subcategories, the linkage isomers and coordination-sphere isomers.
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Conformation
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