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Conformation of hydrogen-bonded dimeric o-methyl-substituted benzoic acids
Marek Gliński1, Ewa Wilczkowska, Izabela D Madura
1Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland.
Abstract:
Molecules of 2,4-dimethylbenzoic acid, C(9)H(10)O(2), form typical centrosymmetric hydrogen-bonded dimers. The carboxyl group is twisted with respect to the benzene ring and the methyl group in the ortho position shows evasive in-plane splaying. The relation between the in-plane splaying and the twist angle of the carboxyl group for various ortho-substituted dimeric derivatives of benzoic acid is presented. It shows how the steric strains are released depending on the numbers and positions of the substituents.
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