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Crystallization and preliminary crystallographic analysis of a plant type III polyketide synthase that produces

Hiroyuki Morita1, Michikazu Tanio, Shin Kondo

  • 1Mitsubishi Kagaku Institute of Life Sciences (MITILS), 11 Minamiooya, Machida, Tokyo 194-8511, Japan.

Acta Crystallographica. Section F, Structural Biology and Crystallization Communications
|April 9, 2008
PubMed

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Benzaldehyde, like formaldehyde, lacks an α hydrogen and cannot enolize to form an enolate. Hence, the reaction of benzaldehyde with a ketone in the presence of an aqueous base forms a single crossed product. This reaction is referred to as Claisen–Schmidt condensation.
As the self-condensation of ketones is generally not favored in basic conditions, the self-condensed products do not form in the reaction between ketones and benzaldehyde. The general reaction of Claisen–Schmidt condensation is...