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Fluctuation theorems

E M Sevick1, R Prabhakar, Stephen R Williams

  • 1Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory 0200 Australia. sevick@rsc.anu.edu.au

Annual Review of Physical Chemistry
|April 9, 2008
PubMed
Summary

Fluctuation theorems reveal how irreversibility arises from reversible dynamics, offering new ways to calculate free-energy changes. These theorems extend thermodynamics to finite systems, crucial for nanotechnology and biology.

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