Amplified emission of phthalocyanine isolated in cryogenic matrices

Laser induced fluorescence spectroscopy of free-base (H(2)Pc) and zinc (ZnPc) phthalocyanines trapped in rare gas and nitrogen matrices reveals a quite unexpected phenomenon with a moderate increase in the laser intensity. In all matrices except Xe, a huge increase occurs in the intensity of an emission band near 755 nm when pumping the S(1) <-- S(0) transition. The band involves a vibrational mode of the ground state, located at 1550 and 1525 cm(-1) for H(2)Pc and ZnPc, respectively. Many of the characteristics of amplified emission (AE) are exhibited by this vibronic transition. Excitation scans recorded for the AE band yield greatly enhanced site selectivity compared to what is obtained in normal fluorescence excitation scans.