N,N'-disubstituted methylenediimidazolium salts: a versatile guest for various macrocycles
Nadim Noujeim1, Loïc Leclercq, Andreea R Schmitzer
1Department of Chemistry, Université de Montréal, Montréal, Québec, Canada.
Abstract:
N,N'-Disubstituted methylenediimidazolium salts allow the formation of flexible inclusion complexes with beta-cyclodextrin, cucurbit[7]uril, tetrapropoxycalix[4]arene, and dibenzo-24-crown-8 ether. Due to the salt nature of the imidazolium guest, the counterion largely determines its solubility in a given solvent. Moreover, by the judicious choice of the imidazolium substituents, inclusion complexes of guest salts were obtained with a variety of macrocyclic hosts, and the binding parameters of the inclusion were determined for each complex.
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