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Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
3D metal-organic frameworks based on elongated tetracarboxylate building blocks for hydrogen storage
Liqing Ma1, Jeong Yong Lee, Jing Li
1Department of Chemistry, CB#3290, University of North Carolina, Chapel Hill, North Carolina 27599, USA.
Inorganic Chemistry
|April 18, 2008
Abstract:
Two 3D metal-organic frameworks (MOFs) with a new biphenol-derived tetracarboxylate linker and Cu(II) and Zn(II) metal-connecting points were synthesized and characterized by single-crystal X-ray crystallographic studies. The two isostructural MOFs exhibit distorted PtS network topology and show markedly different framework stability. The porosity and hydrogen uptake of the frameworks were determined by gas adsorption experiments.
