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Updated: Jul 5, 2026

Atomic Scale Structural Studies of Macromolecular Assemblies by Solid-state Nuclear Magnetic Resonance Spectroscopy
Published on: September 17, 2017
Matrix isolation IR spectroscopic and ab initio studies of C(3)N(-) and related species
Robert Kołos1, Marcin Gronowski, Peter Botschwina
1Institute of Physical Chemistry, Polish Academy of Sciences, Warsaw, Poland. kolos@ichf.edu.pl
Abstract:
Coupled cluster calculations were carried out for C(3)N(-), CCNC(-), C(3)N, CCNC, C(3)N(+), and C(3)O. They support the experimental identification of the C(3)N(-) ion by means of matrix isolation infrared (IR) spectroscopy. The anion was generated in electric discharges through the cyanoacetylene isotopomers HC(3) (14)N, HC(3) (15)N, and (2)HC(3)N, trapped in cryogenic rare gas matrices (Ne, Ar, Kr), and detected via its two most intense IR absorption bands, assigned to the nu(1) and nu(2) stretching vibrations. C(3)N(-) appears to be quite a stable anion, with a vertical detachment energy predicted to be as high as 4.42 eV. A large equilibrium electric dipole moment of 3.10 D facilitates the investigation of C(3)N(-) by microwave spectroscopy and radio astronomy. Various structural parameters and spectroscopic properties have been calculated for all tetra-atomic species considered.
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