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Structure-performance relationships of Rh and RhPd alloy supported catalysts using combined EDE/DRIFTS/MS

Andy J Dent1, John Evans, Steven G Fiddy

  • 1University of Southampton, School of Chemistry, Southampton, UK SO17 1BJ.

Faraday Discussions
|May 2, 2008
PubMed

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The conversion of allylic alcohols into epoxides using the chiral catalyst was discovered by K. Barry Sharpless and is known as Sharpless epoxidation. The use of a chiral catalyst enables the formation of one enantiomer of the product in excess. This chiral catalyst is mainly a chiral complex of titanium tetraisopropoxide and tartrate ester (specific stereoisomer). The stereoisomer used in the chiral catalyst dictates the formation of the enantiomer of the product. In other words, the use of...
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