Related Experiment Video
Updated: Jul 5, 2026

Growth and Electrostatic/chemical Properties of Metal/LaAlO3/SrTiO3 Heterostructures
Published on: February 8, 2018
Optical and structural properties of LaF3 thin films
Martin Bischoff1, Dieter Gäbler, Norbert Kaiser
1Friedrich-Schiller-University, Institute of Applied Physics, Max-Wien-Platz 1, 07743 Jena, Germany. martin.bischoff@iof.fraunhofer.de
Lanthanum fluoride (LaF3) thin films were deposited on CaF2 and silicon substrates. These films exhibit excellent optical and mechanical properties, suitable for various applications.
Area of Science:
- Materials Science
- Thin Film Technology
- Optical Coatings
Background:
- Lanthanum fluoride (LaF3) is a material with significant optical properties.
- Thin film deposition techniques are crucial for creating advanced optical components.
- Understanding the properties of LaF3 thin films is essential for their application in optics.
Purpose of the Study:
- To investigate the optical and mechanical properties of LaF3 thin films.
- To explore the influence of substrate type (CaF2 (111) and silicon) on film characteristics.
- To compare different deposition methods for achieving high-quality LaF3 films.
Main Methods:
- Deposition of LaF3 thin films of varying thicknesses on CaF2 (111) and silicon substrates.
- Low-temperature substrate deposition at 150 degrees C.
- Characterization using optical measurements (transmittance, reflectance, refractive index, extinction coefficient) and mechanical analysis (morphology, crystalline structure).
- Evaluation of boat evaporation and electron beam evaporation techniques.
Main Results:
- LaF3 thin films on CaF2 (111) substrates demonstrated monocrystalline structure and dense, bulk-like morphology.
- Films deposited at 150 degrees C exhibited desirable optical properties.
- Both boat evaporation and electron beam evaporation methods yielded low-loss LaF3 thin films.
Conclusions:
- Low-temperature deposition of LaF3 thin films is feasible and yields high-quality materials.
- LaF3 films on CaF2 (111) possess superior structural and morphological characteristics.
- Electron beam evaporation is a viable alternative to boat evaporation for producing low-loss LaF3 thin films.
Related Concept Videos
Ionic Crystal Structures
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
VSEPR Theory and the Effect of Lone Pairs
Colors and Magnetism
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human eye.
Determination of Crystal Structures
Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
Molecular Shape and Polarity

