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Updated: Jul 5, 2026

Chemical Synthesis of Porous Barium Titanate Thin Film and Thermal Stabilization of Ferroelectric Phase by Porosity-Induced Strain
Published on: March 27, 2018
Phase diagram of the B-B2O3 system at 5 GPa: experimental and theoretical studies
Vladimir L Solozhenko1, Oleksandr O Kurakevych, Vladimir Z Turkevich
1LPMTM-CNRS, Université Paris Nord, 93430 Villetaneuse, France. vls@lpmtm.univ-paris13.fr
Abstract:
X-ray diffraction with synchrotron radiation has been used to study in situ the chemical interaction of beta-rhombohedral boron with boron (III) oxide and phase relations in the B-B2O3 system at pressures up to 6 GPa in the temperature range from 300 to 2800 K. The B-B2O3 system has been thermodynamically analyzed, and its equilibrium phase diagram at 5 GPa has been constructed. Only one thermodynamically stable boron suboxide, B6O, exists in the system. It forms eutectic equilibria with boron and B2O3.
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