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Published on: July 20, 2022
Star-shaped molecule of MnII4O6 core with an St=10 high-spin state. A theoretical and experimental study with XPS,
Sumit Khanra1, Karsten Kuepper, Thomas Weyhermüller
1Max-Planck-Institut für Bioanorganische Chemie, Mülheim an der Ruhr, Germany.
Abstract:
We report a comprehensive study of the electronic and magnetic properties of a star-shaped molecule comprising a MnII4O6 core. One feature of this compound is weak magnetic coupling constants compared to other similar polyoxo compounds. This leads to complicated low-lying magnetic states in which the ground state is not well separated from the upper-lying states, yielding a high-spin molecule with a giant magnetic moment of up to 20 microB/formula unit. We apply X-ray diffraction and magnetometry as well as other X-ray spectroscopic techniques, namely, X-ray photoelectron spectroscopy, X-ray magnetic circular dichroism, and X-ray emission spectroscopy. We compare our experimental results with ab initio electronic band structure calculations as well as the localized electronic structure around the Mn2+ ions with charge-transfer multiplet calculations.
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