CuO and Ag2O/CuO catalyzed oxidation of aldehydes to the corresponding carboxylic acids by molecular oxygen
Qingyong Tian1, Daxin Shi, Yaowu Sha
1The Key Laboratory of Bioorganic Phosphorous Chemistry and Chemical Biology, Department of Chemistry, Tsinghua University, Beijing 100084, PR China.
Abstract:
Furfural was oxidized to furoic acid by molecular oxygen under catalysis by 150 nm-sized Ag(2)O/CuO (92%) or simply CuO (86.6%). When 30 nm-size catalyst was used,the main product was a furfural Diels-Alder adduct. Detailed reaction conditions and regeneration of catalysts were investigated. Under optimal conditions, a series of aromatic and aliphatic aldehydes were oxidized to the corresponding acids in good yields.
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