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The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
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Synthesis, Structure and Antitumour Properties of a New 1,2-Propylenediaminetetraacetate-Ruthenium(III) Compound

R Vilaplana1, M A Romero, M Quirós

  • 1Dpto. de Quífmica Inorgánica F. de Química Universidad de Sevilla Sevilla 41071 Spain.

Metal-Based Drugs
|January 1, 1995
PubMed

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Aromatic Hydrocarbon Cations: Structural Overview01:18

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Cycloheptatriene is a neutral monocyclic unsaturated hydrocarbon that consists of an odd number of carbon atoms and an intervening sp3 carbon in the ring. The three double bonds in the ring correspond to 6 π electrons, which is a Huckel number, and therefore satisfies the criteria of 4n + 2 π electrons. However, the intervening sp3 carbon disrupts the continuous overlap of p orbitals. As a result, cycloheptatriene is not aromatic.
Removing one hydrogen from the intervening CH2 group with both...