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From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
Published on: March 24, 2018
Dibenzylimidazolium halides: from complex molecular network in solid state to simple dimer in solution and in gas
Loïc Leclercq1, Andreea R Schmitzer
1Department of Chemistry, Université de Montréal, C.P. 6128 Succursale Centre-ville, Montréal, Québec H3C 3J7, Canada.
Abstract:
1,3-Dibenzylimidazolium bromide has been synthesized and the nature of the interactions between cations and anions has been studied in the solid state, in solution and in the gas phase. The cohesion of the crystal is ensured by a combination of hydrogen bonds, and aromatic stacking interactions. In solution and in the gas phase, the supramolecular structural organization due to T-stacking is maintained to a great extent.
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