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Published on: September 18, 2016
Bowl-to-bowl inversion of sumanene derivatives
Toru Amaya1, Hiroyuki Sakane, Toshiko Muneishi
1Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Osaka, 565-0871, Japan.
Abstract:
The bowl-to-bowl inversion of the non-planar bowl-shaped compounds derived from sumanene as a fullerene C3v fragment was found to be slow and tuned by a solvent, and the benzylic mono- and di-anions inverted even more slowly.
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