Novel spirobisindanes for use as precursors to polymers of intrinsic microporosity
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Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
Mariolino Carta1, Kadhum J Msayib, Peter M Budd
1School of Chemistry, Cardiff University, Cardiff CF10 3AT, UK. mckeownnb@cardiff.ac.uk
Organic Letters
|June 4, 2008
Abstract:
The synthesis of novel spirobisindane-based monomers for the preparation of polymers of intrinsic microporosity (PIMs) with bulky, rigid substituents is described. Polymers derived from monomers containing spiro-linked fluorene substituents display enhanced solubility and microporosity due to additional frustration of packing in the solid state.
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