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Related Concept Videos

Atomic Nuclei: Nuclear Spin State Population Distribution01:14

Atomic Nuclei: Nuclear Spin State Population Distribution

Near absolute zero temperatures, in the presence of a magnetic field, the majority of nuclei prefer the lower energy spin-up state to the higher energy spin-down state. As temperatures increase, the energy from thermal collisions distributes the spins more equally between the two states. The Boltzmann distribution equation gives the ratio of the number of spins predicted in the spin −½ (N−) and spin +½ (N+) states.
¹H NMR: Interpreting Distorted and Overlapping Signals01:02

¹H NMR: Interpreting Distorted and Overlapping Signals

Spin systems where the difference in chemical shifts of the coupled nuclei is greater than ten times J are called first-order spin systems. These nuclei are weakly coupled, and their chemical shifts and coupling constant can generally be estimated from the well-separated signals in the spectrum.
As Δν decreases and the signals move closer, the doublets appear increasingly distorted. The intensities of the inner lines increase at the cost of those of the outer lines as the signals are slanted or...
Atomic Nuclei: Nuclear Spin State Overview01:03

Atomic Nuclei: Nuclear Spin State Overview

NMR-active nuclei have energy levels called 'spin states' that are associated with the orientations of their nuclear magnetic moments. In the absence of a magnetic field, the nuclear magnetic moments are randomly oriented, and the spin states are degenerate. When an external magnetic field is applied, the spin states have only 2 + 1 orientations available to them. A proton with = ½ has two available orientations. Similarly, for a quadrupolar nucleus with a nuclear spin value of one, the...
Atomic Nuclei: Types of Nuclear Relaxation01:28

Atomic Nuclei: Types of Nuclear Relaxation

Nuclear relaxation restores the equilibrium population imbalance and can occur via spin–lattice or spin–spin mechanisms, which are first-order exponential decay processes.
In spin–lattice or longitudinal relaxation, the excited spins exchange energy with the surrounding lattice as they return to the lower energy level. Among several mechanisms that contribute to spin–lattice relaxation, magnetic dipolar interactions are significant. Here, the excited nucleus transfers energy to a nearby...
Atomic Nuclei: Nuclear Relaxation Processes01:23

Atomic Nuclei: Nuclear Relaxation Processes

In the absence of an external magnetic field, nuclear spin states are degenerate and randomly oriented. When a magnetic field is applied, the spins begin to precess and orient themselves along (lower energy) or against (higher energy) the direction of the field. At equilibrium, a slight excess population of spins exists in the lower energy state. Because the direction of the magnetic field is fixed as the z-axis,  the precessing magnetic moments are randomly oriented around the z-axis. This...
Other Nuclides: 31P, 19F, 15N NMR01:16

Other Nuclides: 31P, 19F, 15N NMR

Many organic, inorganic, and biological molecules contain spin-half nuclei such as nitrogen-15, fluorine-19, and phosphorus-31. As a result, NMR studies of these nuclei have found extensive applications in chemical and biological research.
While fluorine-19 and phosphorous-31 have high natural abundances (100%) and positive gyromagnetic ratios, nitrogen-15 has a low natural abundance and a negative gyromagnetic ratio. However, nitrogen-15 is still preferred over nitrogen-14 (which has a high...

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Related Experiment Video

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Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
08:55

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses

Published on: June 7, 2018

Simple empirical order parameter for a first-order quantum phase transition in atomic nuclei.

Dennis Bonatsos1, E A McCutchan, R F Casten

  • 1Institute of Nuclear Physics, National Center for Scientific Research Demokritos, GR-15310 Aghia Paraskevi, Attiki, Greece.

Physical Review Letters
|June 4, 2008
PubMed
Summary

A new order parameter, the ratio of 6+ to 0+ state energies, effectively distinguishes nuclear phase transitions. This ratio shows unique behavior in the critical region, indicating potential underlying symmetries.

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Area of Science:

  • Nuclear physics
  • Atomic nuclei structure
  • Quantum mechanics

Background:

  • Phase transitions in atomic nuclei are crucial for understanding nuclear structure.
  • Distinguishing between first- and second-order phase transitions is essential.
  • Existing order parameters may lack simplicity or ease of measurement.

Purpose of the Study:

  • To introduce a simple, empirical, and easily measurable order parameter for first-order phase transitions in atomic nuclei.
  • To differentiate between first- and second-order nuclear phase transitions.
  • To investigate the behavior of this parameter in the critical region.

Main Methods:

  • Calculating the ratio of the energies of the first excited 6+ and 0+ states.
  • Analyzing data from Nd-Dy isotopes.
  • Utilizing the interacting boson approximation (IBA) model in the large N_B limit.

Main Results:

  • The proposed ratio of 6+ to 0+ state energies serves as an effective order parameter.
  • This parameter distinguishes between first- and second-order transitions.
  • A special value of this ratio is observed in the critical region for Nd-Dy data.
  • The interacting boson approximation model reveals repeating degeneracies between alternate yrast and successive 0+ states near first-order phase transitions.

Conclusions:

  • The 6+/0+ energy ratio is a viable order parameter for nuclear phase transitions.
  • The observed degeneracies in the critical region suggest a possible underlying symmetry in atomic nuclei.
  • This finding aids in the characterization and understanding of nuclear structure and dynamics.