Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Spin–Spin Coupling: Two-Bond Coupling (Geminal Coupling)01:20

Spin–Spin Coupling: Two-Bond Coupling (Geminal Coupling)

Two NMR-active nuclei bonded to a central atom can be involved in geminal or two-bond coupling. Geminal coupling is commonly seen between diastereotopic protons in chiral molecules and unsymmetrical alkenes, among others.
The central atom need not be NMR-active because its electrons are affected by the electron polarization of the spin-active atoms. However, spin information is transmitted less effectively than in one-bond coupling, and 2J values are usually weaker than 1J values. The energy of...
Spin–Spin Coupling: One-Bond Coupling01:17

Spin–Spin Coupling: One-Bond Coupling

Coupling interactions are strongest between NMR-active nuclei bonded to each other, where spin information can be transmitted directly through the pair of bonding electrons. While nuclei polarize their electrons to the opposite spins, the bonding electron pair has opposite spins. Configurations with antiparallel nuclear spins are expected to be lower in energy. When coupling makes antiparallel states more favorable, J is considered to have a positive value. The one-bond coupling constant, 1J,...
The Pauli Exclusion Principle03:06

The Pauli Exclusion Principle

The arrangement of electrons in the orbitals of an atom is called its electron configuration. We describe an electron configuration with a symbol that contains three pieces of information:
Spin–Spin Coupling: Three-Bond Coupling (Vicinal Coupling)01:22

Spin–Spin Coupling: Three-Bond Coupling (Vicinal Coupling)

Vicinal or three-bond coupling is commonly observed between protons attached to adjacent carbons. Here, nuclear spin information is primarily transferred via electron spin interactions between adjacent C‑H bond orbitals. This generally favors the antiparallel arrangement of spins, so 3J values are usually positive.
The extent of coupling depends on the C‑C bond length, the two H‑C‑C angles, any electron-withdrawing substituents, and the dihedral angle between the involved orbitals. The...
Atomic Nuclei: Nuclear Spin State Overview01:03

Atomic Nuclei: Nuclear Spin State Overview

NMR-active nuclei have energy levels called 'spin states' that are associated with the orientations of their nuclear magnetic moments. In the absence of a magnetic field, the nuclear magnetic moments are randomly oriented, and the spin states are degenerate. When an external magnetic field is applied, the spin states have only 2 + 1 orientations available to them. A proton with = ½ has two available orientations. Similarly, for a quadrupolar nucleus with a nuclear spin value of one, the...
Spin–Spin Coupling Constant: Overview01:08

Spin–Spin Coupling Constant: Overview

In bromoethane, the three methyl protons are coupled to the two methylene protons that are three bonds away. In accordance with the n+1 rule, the signal from the methyl protons is split into three peaks with 1:2:1 relative intensities. The methylene protons appear as a quartet, with the relative intensities of 1:3:3:1.
Qualitatively, any spin plus-half nucleus polarizes the spins of its electrons to the minus-half state. Consequently, the paired electron in the hydrogen–carbon bond must have a...

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

The impact of elective surgery restrictions during the COVID-19 (coronavirus disease 2019) pandemic on shoulder and elbow surgery: patient perceptions.

Journal of shoulder and elbow surgery·2022
Same author

Establishing maximal medical improvement following aseptic revision of shoulder arthroplasty.

Journal of shoulder and elbow surgery·2022
Same author

Does Velocity Increase From Flat-Ground to Mound Work During a Lighter Baseball Training Program?

The Journal of the American Academy of Orthopaedic Surgeons·2021
Same author

Interaction Between Age and Change in Velocity During a Baseball Training Program.

Orthopaedic journal of sports medicine·2020
Same author

Factors affecting return to sport following hamstrings anterior cruciate ligament reconstruction in non-elite athletes.

European journal of orthopaedic surgery & traumatology : orthopedie traumatologie·2019
Same author

Morel-Lavallée Lesion: Presenting Etiology of Chronic Myelogenous Leukemia in an Adolescent Athlete: A Case Report.

JBJS case connector·2017

Related Experiment Video

Updated: Jul 4, 2026

A Photonic System for Generating Unconditional Polarization-Entangled Photons Based on Multiple Quantum Interference
07:56

A Photonic System for Generating Unconditional Polarization-Entangled Photons Based on Multiple Quantum Interference

Published on: September 5, 2019

Single-copy entanglement in a gapped quantum spin chain.

Christopher Hadley1

  • 1Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT, United Kingdom.

Physical Review Letters
|June 4, 2008
PubMed
Summary

Single-copy entanglement in gapped quantum systems, like the spin-S Affleck-Kennedy-Lieb-Tasaki chain, equals the von Neumann entropy. This means all system entanglement can be distilled from just one specimen.

Area of Science:

  • Quantum Information Theory
  • Condensed Matter Physics

Background:

  • Single-copy entanglement quantifies distillable entanglement from one quantum system copy.
  • For critical spin chains, single-copy entanglement is half the von Neumann entropy.
  • The behavior of single-copy entanglement in gapped systems remains an open question.

Purpose of the Study:

  • To investigate single-copy entanglement in gapped quantum systems.
  • To determine if all entanglement can be distilled from a single specimen in gapped systems.

Main Methods:

  • Analysis of the spin-S Affleck-Kennedy-Lieb-Tasaki chain, a paradigmatic gapped system.
  • Comparison of single-copy entanglement with von Neumann entropy.

Main Results:

More Related Videos

Nanofabrication of Gate-defined GaAs/AlGaAs Lateral Quantum Dots
15:47

Nanofabrication of Gate-defined GaAs/AlGaAs Lateral Quantum Dots

Published on: November 1, 2013

Related Experiment Videos

Last Updated: Jul 4, 2026

A Photonic System for Generating Unconditional Polarization-Entangled Photons Based on Multiple Quantum Interference
07:56

A Photonic System for Generating Unconditional Polarization-Entangled Photons Based on Multiple Quantum Interference

Published on: September 5, 2019

Nanofabrication of Gate-defined GaAs/AlGaAs Lateral Quantum Dots
15:47

Nanofabrication of Gate-defined GaAs/AlGaAs Lateral Quantum Dots

Published on: November 1, 2013

  • Single-copy entanglement for the spin-S Affleck-Kennedy-Lieb-Tasaki chain is equal to its von Neumann entropy.
  • This implies that all entanglement in this gapped system is distillable from a single copy.
  • Conclusions:

    • The relationship between single-copy entanglement and von Neumann entropy differs between critical and gapped systems.
    • All entanglement in the studied gapped spin chain can be extracted from a single system instance.