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Updated: Jul 4, 2026

The Preparation and Properties of Thermo-reversibly Cross-linked Rubber Via Diels-Alder Chemistry
Published on: August 25, 2016
Five-year comparative study of highly cross-linked (crossfire) and traditional polyethylene
Amar D Rajadhyaksha1, Cristian Brotea, Yeukkei Cheung
1Westchester Medical Center, New York Medical College Department of Orthopaedics, Valhalla, New York 10595, USA.
Abstract:
The purpose of this study was to compare the linear penetration rates of a highly cross-linked ultra-high-molecular-weight polyethylene to traditional polyethylene. Twenty-seven highly cross-linked components were matched to 27 traditional polyethylene components with respect to age, sex, body mass index, and activity level. Each group was followed up for a mean of approximately 6 years. Linear penetration was measured using Martell's computerized technique (J Bone Joint Surg Am 1997;79:1635). The mean total penetration was 0.283 mm (SD, 0.253) for the highly cross-linked group. The mean total penetration for the traditional polyethylene was 0.696 mm (SD, 0.402). This difference was highly significant (P < or = .001). Our experience demonstrates a 59% reduction in total penetration of highly cross-linked polyethylene when compared with traditional polyethylene at a minimum of 5 years.
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