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Updated: Jul 4, 2026

Synthesis of Programmable Main-chain Liquid-crystalline Elastomers Using a Two-stage Thiol-acrylate Reaction
Published on: January 19, 2016
Effect of crosslinking on the photonic bandgap in deformable cholesteric elastomers
Yoshihito Hirota1, Yan Ji, Francesca Serra
1Cavendish Laboratory, University of Cambridge, J.J. Thomson Avenue, Cambridge, CB3 0HE, UK.
Abstract:
Cholesteric liquid crystal (CLC) application for tunable lasing devices has become a subject of study for many research groups. In particular, embedding the liquid crystal in an elastomer allows tunability by simple mechanical stretching. Here we report a study on the dependence of the selective reflection band on the stretching together with measurements of film relaxation after stretching, and we try to discuss and elucidate the role of crosslinking in the polymer matrix. We obtained laser devices made with cholesteric liquid crystal elastomers in a three-layer configuration, where an isotropic layer containing a laser dye is sandwiched between two CLC elastomers: in this work we show some preliminary but quantitative results on laser tunability.
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