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Reductive coupling of metal triangles in sandwich complexes

Tetsuro Murahashi1, Yasuhiro Hashimoto, Koji Chiyoda

  • 1Department of Applied Chemistry, Graduate School of Engineering, Osaka University, and PRESTO, Japan Science and Technology Agency (JST), Suita, Osaka 565-0871, Japan. tetsu@chem.eng.osaka-u.ac.jp

Journal of the American Chemical Society
|June 14, 2008
PubMed
Summary

The one-electron reduction of palladium complexes forms novel hexapalladium dimers with a unique bitriangle structure. These air-sensitive dimers are stable in acetonitrile but require careful handling.

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