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Scanning tunneling microscopy investigation of a supramolecular self-assembled three-dimensional chiral prism on a

Qun-Hui Yuan1, Cun-Ji Yan, Hui-Juan Yan

  • 1Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences (CAS), Beijing, China 100080.

Journal of the American Chemical Society
|June 14, 2008
PubMed

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Chirality is most prevalent in carbon-based tetrahedral compounds, but this important facet of molecular symmetry extends to sp3-hybridized nitrogen, phosphorus and sulfur centers, including trivalent molecules with lone pairs. Here, the lone pair behaves as a functional group in addition to the other three substituents to form an analogous tetrahedral center that can be chiral.
A consequence of chirality is the need for enantiomeric resolution. While this is theoretically possible for all...