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Updated: Jul 4, 2026
11:27
Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
Robust metal-organic framework enforced by triple-framework interpenetration exhibiting high H2 storage density
Ming Xue1, Shengqian Ma, Zhao Jin
1State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Jilin University, Changchun, China.
Inorganic Chemistry
|June 28, 2008
Summary
A novel metal-organic framework, Zn2(CNC)2(DPT).G, was synthesized. This robust material demonstrates significant hydrogen uptake and storage capacity, making it promising for hydrogen storage applications.
Area of Science:
- Materials Science
- Chemistry
- Nanotechnology
Background:
- Metal-organic frameworks (MOFs) are porous materials with potential applications in gas storage.
- Developing robust MOFs with high storage capacity is crucial for practical applications.
Purpose of the Study:
- To synthesize and characterize a new microporous metal-organic framework.
- To evaluate the hydrogen uptake and storage properties of the synthesized MOF.
Main Methods:
- Synthesis of Zn2(CNC)2(DPT).G using 4-Carboxycinnamic (CNC) and 3,6-Di-4-pyridyl-1,2,4,5-tetrazine (DPT).
- Structural characterization using X-ray diffraction.
- Hydrogen gas uptake measurements at 1 atm and 77 K.
Main Results:
- The MOF features a triply interpenetrated primitive cubic net with 1D pores (approx. 3.7 A).
- The framework exhibits high robustness due to triple interpenetration.
- Activated MOF (1b) achieved 1.28 wt % hydrogen uptake.
- A high hydrogen storage density of 95.2% was observed.
Conclusions:
- The synthesized MOF, Zn2(CNC)2(DPT).G, is a robust and porous material.
- The MOF demonstrates excellent hydrogen storage capabilities, indicating its potential for practical hydrogen storage solutions.
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