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Updated: Jul 4, 2026

Calcium Carbonate Formation in the Presence of Biopolymeric Additives
Published on: May 14, 2019
Nucleation of calcium carbonate as polymorphic crystals in the presence of lipid A-diphosphate
Abstract:
The well-defined structure of lipid A-diphosphate in aqueous solutions provides a way of observing the formation of calcium carbonate crystals. The crystals are either tetrahedral or rhombohedral calcite at a volume fraction of phi = 5.4 x 10 (-4) at pH 5.8 or the vaterite polymorph of CaCO(3) at a volume fraction of phi = 7.8 x 10 (-4) at pH 5.8. In both cases, nucleation, adsorption pH, and the shape-dependent template of lipid A-diphosphate control the formation of the calcite and vaterite.
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