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Updated: Jul 3, 2026

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Energetic N,N,N',N'-tetraaminopiperazinium salts
Haixiang Gao1, Yangen Huang, Brendan Twamley
1Department of Applied Chemistry, China Agricultural University, Beijing, China.
Abstract:
The formation of terraminopiperazinium salts using water as solvent provides a green, straightforward approach to highly energetic salts that exhibit good thermal stabilities and moderate densities. The N,N,N',N'-tetraaminopiperazinium cation was selected for this study because of its high nitrogen-nitrogen bond content and its hign positive near or formation. Theoretical and empirical calculations on energetic salts based on this nitrogen-rich cation reveal them to have high positive molar enthalpies of formation, as high as 1034.0 kJ mol(-1), supporting the application of these new salts as potential energetic materials.
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