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Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
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Concise total synthesis of (+)-crocacin C.

Gopal Sirasani1, Tapas Paul, Rodrigo B Andrade

  • 1Department of Chemistry, Temple University, Philadelphia, Pennsylvania 19122, USA.

The Journal of Organic Chemistry
|July 18, 2008
PubMed
Summary

Researchers synthesized the cytotoxic natural product (+)-crocacin C using a 10-step linear synthesis. This efficient method avoided protecting groups, starting from readily available chiral materials.

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