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Updated: Jul 3, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
Published on: April 19, 2019
Direct oxidative cyanation based on the concept of site isolation
Toshiki Tajima1, Atsushi Nakajima
1Global Edge Institute, Tokyo Institute of Technology, Yokohama 226-8502, Japan. tajima.t.ac@m.titech.ac.jp
Abstract:
On the basis of the concept of site isolation, we have successfully demonstrated direct oxidative cyanation of various organic compounds, which even have higher oxidation potentials compared to that of cyanide, by using a polystyrene-supported quaternary ammonium cyanide.
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