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Updated: Jul 3, 2026

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
Control over phase behavior and solution structure of hairy-rod polyfluorene by means of side-chain length and
M Knaapila1, R Stepanyan, M Torkkeli
1Department of Physics, Institute for Energy Technology, P.O. Box 40, NO-2027 Kjeller, Norway. matti.knaapila@ife.no
Abstract:
We present guidelines on how the solution structure of pi -conjugated hairy-rod polyfluorenes is controlled by the side-chain length and branching. First, the semiquantitative mean-field theory is formulated to predict the phase behavior of the system as a function of side-chain beads (N). The phase transition at N=N{ *} separates a lyotropic phase with solvent coexistence (N
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