Influence of nanotips on the hydrophilicity of metallic nanorod surfaces

The hydrophilicity of vertically aligned metal nanorods with sharp nanotips were investigated experimentally. Ruthenium and platinum nanorod arrays were deposited on flat silicon substrates using oblique angle sputter deposition. We show that the effects of nanotips on nanorods should be considered in the "hemiwicking" model for hydrophilic metallic samples. With the influence of nanotips, we successfully explained the experimental contact angles of water sessile drops on metallic nanorod surfaces. Our experiments confirm that the shape of the nanorods is an important parameter in determining the hydrophilicity of the nanostructured surfaces.